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The Improvement of Technology for Synthesising 1,4,6,9 tetranitro 1,4,6,9 tetrazabicyclo decane(PDF)

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

Issue:
1997年02期
Page:
18-21
Research Field:
Publishing date:

Info

Title:
The Improvement of Technology for Synthesising 1,4,6,9 tetranitro 1,4,6,9 tetrazabicyclo decane
Author(s):
LuMing LuChunxu WeiYunyang LiZhiping
School of Chemical Engineering,NUST,Nanjing 210094
Keywords:
ex plosiv es nit rogen heter ocy clics nit ramine synthesis techno logy condensat io n react io n nit rat io n react ion
PACS:
O626
DOI:
-
Abstract:
In this paper , the synthesis of 1, 4, 6, 9-tet razabicyclo [ 4, 4, 0] decane ( 1) fr om ethylenediamine, g lyox al is r eported, the y ield is 77. 5 % . Nit ratio n of the compound ( 1) w ith nit ric acid in acetic anhydride gave 1, 4, 6, 9-tet ranitro-1, 4, 6, 9-tet razabicyclo [ 4, 4, 0] decane ( 2) , the y ield is 82. 8 % . T he total y ield of the compo und ( 2) is as hig h as 64. 0 % , the melt ing point is 224~ 230 ℃. T he mechanism of co ndensat ion react ion for sy nthesising compound ( 1) and the factor s affect ing the co ndensat ion react ion are studied. As fo r the nit rat ion r eact ion of compound ( 1) , the af fect ing facto rs and the react ion mechanism are al so discussed.

References:

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3 陆明, 吕春绪, 魏运洋. 2, 5, 7, 9-四硝基-2, 5, 7, 9-四氮杂双环[ 4, 3, 0] 壬-8-酮的合成及其性能. 南京理工大学学报, 1995, 19( 4) : 325~327
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Memo

Memo:
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Last Update: 2013-03-29