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Crystal Structure of Bis(3-methoxy-4-hydroxy) Benzaldehyde Dihydroxide Zinc(Ⅱ) Complex(PDF)

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

Issue:
2004年03期
Page:
303-306
Research Field:
Publishing date:

Info

Title:
Crystal Structure of Bis(3-methoxy-4-hydroxy) Benzaldehyde Dihydroxide Zinc(Ⅱ) Complex
Author(s):
WANG Jun 12 BEI Feng li 1LI Ren yu 1YANG Xu jieLU Lu de 1WANG Xin 1
1.School of Chemical Engineering,NUST,Nanjing 210094,China;2.Department of Police Technique, Jiangsu Police Institude , Nanjing, 210012,China
Keywords:
zinc( Ⅱ ) complex crystal st ructure bis( 3- methox y- 4- hydroxy) benzaldehy
PACS:
O641.4
DOI:
-
Abstract:
Bis ( 3- methox y- 4 - hydrox y) benzaldehyde dihydrox ide zinc( Ⅱ ) complex has been synthesized and characterized by IR and single-crystal X- ray analysis. The crystal is monoclinic, space g roup Cc w ith a = 2. 216 7( 4) nm, b = 1. 054 0( 2) nm, c = 0. 780 0( 2) nm, B= 106. 92( 3)°, Z = 4, R 1 = 0. 039 0, w R 2 = 0. 091 6 . The cent ral zinc atom is octahedrally coordinated by an arrangement of six O atoms. In the crystal latt ice, the molecules form a three-dimension netw ork st ructure throug h hydrogen bonds. The C ) H ,O intermolecular hydrogen bonds and van der w aals interact ion connect the t itle complex to form net supermolecular st ructure.

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Last Update: 2013-03-11