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The Structure of Bis(O-cyclohexyldithiocarbonatio-S,S’) (1,10-phenanthroline-N1,N10) Copper(Ⅱ) Complex(PDF)

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

Issue:
2004年03期
Page:
307-310
Research Field:
Publishing date:

Info

Title:
The Structure of Bis(O-cyclohexyldithiocarbonatio-S,S’) (1,10-phenanthroline-N1,N10) Copper(Ⅱ) Complex
Author(s):
HAN Qiao fengMA Wei huaLUO Yuan xiangYANG Xu jieWANG Xin
School of Chemical Engineering,NUST,Nanjing 210094,China
Keywords:
xanthate 1 10-phenanthroline crystal st ructure
PACS:
O641.4
DOI:
-
Abstract:
The t it le compound, [ Cu( phen) ( C6H11OCSS) 2] is synthesized and its crystal st ructure is determined by X- ray diff ract ion. The crystal is monoclinic of space g roup P 21/ c , w ith parameters a = 1. 228 0( 3) nm, b = 1. 861 0( 4) nm, c = 1. 286 0( 3) , B= 104. 50( 3) , V = 21845 3( 10) nm3 and Z = 4. Cu atom is six-coordinated by two nit rogen atoms from phenanthroline ligand and four sulfur atoms from tw o ( O-cy clohex yldithiocarbonatio) anions. The inf ra red and ult raviolet-visible spectroscopic results supported the crystal structure.

References:

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Last Update: 2013-03-11