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Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum(PDF)

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

Issue:
2004年06期
Page:
648-652
Research Field:
Publishing date:

Info

Title:
Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum
Author(s):
MA Jian-qiBEI Feng-liLI Jun-qiYANG Xu-jie LU Lu-deWANG Xin
Materials Chemistry Laboratory, NUST, Nanjing 210094,China
Keywords:
bis( diiso- propylcarbamodithioato- S S’ ) Molybdenum solid phase reaction at room temperature crystal structure
PACS:
O627;O641.4
DOI:
-
Abstract:
Bis( diiso-propylcarbamodithioato- S, S ) Molybdenum was synthesized by the solid phase react ion of phosphomolybdic acid and diiso-propylcarbamodithioato sodium at room temperature. The product was characterized by IR, Xray powder diffract ion and TG- DTA. Its single crystal was deter mined by X ray single crystal diffraction. The crystal belongs to monoclinic system with a space group P21/ c, a = 0. 815 70( 16) nm, b = 1. 784 4( 4) nm, c = 1. 564 8( 5) nm, β= 110. 38( 3), V = 2. 135 1( 9) nm 3 , Z = 4, Dc = 1. 396 Mg/ m 3 , F( 000) = 928, μ= 1. 002 mm - 1 , R = 0. 088 8, Rw = 0. 144 2, GOF = 1. 092.

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Last Update: 2013-03-11