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《南京理工大学学报》（自然科学版）[ISSN:1005-9830/CN:32-1397/N]

Issue:

2004年06期

Page:

648-652

Research Field:

Publishing date:

Info

Title:

Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum

Author(s):

MA Jian-qi; BEI Feng-li; LI Jun-qi; YANG Xu-jie;  LU Lu-de; WANG Xin

Materials Chemistry Laboratory, NUST, Nanjing 210094,China

Keywords:

bis( diiso- propylcarbamodithioato- S;  S’ ) Molybdenum;  solid phase reaction at room temperature;  crystal structure

PACS:

O627;O641.4

DOI:

-

Abstract:

Bis( diiso-propylcarbamodithioato- S, S ) Molybdenum was synthesized by the solid phase react ion of phosphomolybdic acid and diiso-propylcarbamodithioato sodium at room temperature. The product was characterized by IR, Xray powder diffract ion and TG- DTA. Its single crystal was deter mined by X ray single crystal diffraction. The crystal belongs to monoclinic system with a space group P21/ c, a = 0. 815 70( 16) nm, b = 1. 784 4( 4) nm, c = 1. 564 8( 5) nm, β= 110. 38( 3), V = 2. 135 1( 9) nm 3 , Z = 4, Dc = 1. 396 Mg/ m 3 , F( 000) = 928, μ= 1. 002 mm - 1 , R = 0. 088 8, Rw = 0. 144 2, GOF = 1. 092.

References:

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Memo

Memo:

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Common functions

Last Update: 2013-03-11