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Synthesis,structure and property of 2D znic complex(PDF)

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

Issue:
2017年02期
Page:
232-
Research Field:
Publishing date:

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Title:
Synthesis,structure and property of 2D znic complex
Author(s):
Huang Qiuying1Lin Xiaoyi2Meng Xiangru3
1.Department of Chemical Engineering,Henan Polytechnic Institute,Nanyang 473009,China; 2.No 1 Middle School of Nanyang,Nanyang 473000,China; 3.College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450001,China
Keywords:
Zn(II)-complex 2-(1H-imidazol-1-methyl)-1H-benzimidazole sodium benzene-123-tricarboxylate crystal structure thermal stability fluorescence property
PACS:
O614
DOI:
10.14177/j.cnki.32-1397n.2017.41.02.015
Abstract:
A new 2D complex with the formula {[Zn6(imb)4(btc)4]·7.5H2O}n(1)is synthesized through the solvothermal reaction of Zn(NO3)2·6H2O,2-(1H-imidazol-1-methyl)-1H-benzimidazole(imb)and sodium benzene-1,2,3-tricarboxylate(Na3btc)at 120 ℃,and it is structurally characterized by the elemental analysis,the infrared spectroscopy(IR)and the thermogravimetric analysis.The single-crystal X-ray analysis reveals that the complex 1 crystallizes in the monoclinic space group P21/c.Upon excitation at 312 nm,complex powders exhibits intense emission at 422 nm and room temperature for the solid state.

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Last Update: 2017-04-30