[1]陆明,吕春绪,魏运洋,等.1,4,6,9-四硝基-1,4,6,9-四氮杂双环[4,4,0]癸烷合成工艺改进[J].南京理工大学学报(自然科学版),1997,(02):18-21.
　LuMing LuChunxu WeiYunyang LiZhiping.The Improvement of Technology for Synthesising 1,4,6,9 tetranitro 1,4,6,9 tetrazabicyclo decane[J].Journal of Nanjing University of Science and Technology,1997,(02):18-21.
点击复制

1,4,6,9-四硝基-1,4,6,9-四氮杂双环[4,4,0]癸烷合成工艺改进()
分享到：

《南京理工大学学报》（自然科学版）[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
1997年02期
页码:
18-21
栏目:
出版日期:
1997-04-30

文章信息/Info

Title:
The Improvement of Technology for Synthesising 1,4,6,9 tetranitro 1,4,6,9 tetrazabicyclo decane
作者:
陆明; 吕春绪; 魏运洋; 李志平
南京理工大学化工学院, 南京210094
Author(s):
LuMing LuChunxu WeiYunyang LiZhiping
School of Chemical Engineering,NUST,Nanjing 210094
关键词:
炸药;  氮杂环化合物;  硝胺;  合成;  工艺;  缩合反应;  硝化反应
Keywords:
ex plosiv es;  nit rogen heter ocy clics;  nit ramine;  synthesis;  techno logy ;  condensat io n react io n;  nit rat io n react ion
分类号:
O626
摘要:
以乙二胺和乙二醛为原料，合成了１，４，６，９－四氮杂双环［４，４，０］癸烷（１），反应得率为７７．５％。母体化合物（１）在硝酸－乙酐体系中硝化，制得１，４，６，９－四硝基－１，４，６，９－四氮杂双环［４，４，０］癸烷（２），反应得率为８２．８％，制备化合物（２）的总得率高达６４．０％，熔点为２２４～２３０℃。文中研究了合成母体化合物（１）的缩合反应的机理和影响因素，讨论了母体化合物（１）硝化反应的影响因素和反应历程
Abstract:
In this paper , the synthesis of 1, 4, 6, 9-tet razabicyclo [ 4, 4, 0] decane ( 1) fr om ethylenediamine, g lyox al is r eported, the y ield is 77. 5 % . Nit ratio n of the compound ( 1) w ith nit ric acid in acetic anhydride gave 1, 4, 6, 9-tet ranitro-1, 4, 6, 9-tet razabicyclo [ 4, 4, 0] decane ( 2) , the y ield is 82. 8 % . T he total y ield of the compo und ( 2) is as hig h as 64. 0 % , the melt ing point is 224～ 230 ℃. T he mechanism of co ndensat ion react ion for sy nthesising compound ( 1) and the factor s affect ing the co ndensat ion react ion are studied. As fo r the nit rat ion r eact ion of compound ( 1) , the af fect ing facto rs and the react ion mechanism are al so discussed.

参考文献/References:

1　宋洪昌. 火药用单质炸药的分子结构与火药燃速压强指数的相关性. 含能材料, 1993, 1( 2) : 28～34
2　杨春盛. 四硝基并哌嗪的研究. 火炸药, 1984( 5) : 1～5
3　陆明, 吕春绪, 魏运洋. 2, 5, 7, 9-四硝基-2, 5, 7, 9-四氮杂双环[ 4, 3, 0] 壬-8-酮的合成及其性能. 南京理工大学学报, 1995, 19( 4) : 325～327
4　吕春绪. 硝化理论. 南京: 江苏科技出版社, 1993. 25～28

相似文献/References:

[1]赵雪,芮久后,冯顺山.RDX 颗粒形态对RDX 基熔铸炸药性能的影响[J].南京理工大学学报(自然科学版),2011,(05):714.
　ZHAO Xue,RUI Jiu-hou,FENG Shun-shan.Effects of RDX Physical Morphology on Properties of RDX Base Melt-cast Explosive[J].Journal of Nanjing University of Science and Technology,2011,(02):714.
[2]陆明,沈薇.2,4,7,9-四硝基-2,4,7,9-四氮杂双环[4,3,0]壬酮合成工艺改进[J].南京理工大学学报(自然科学版),2003,(02):196.
　LuMing ShenWei.Technical Improvement for Synthesizing 2,4,7,9- tetranitro-2,4,7,9-tetrazabicyclo [4,3,0] nonanone[J].Journal of Nanjing University of Science and Technology,2003,(02):196.
[3]陆明,吕春绪,魏运洋.2,3-二羟基哌嗪与几种氨基化合物的缩合反应研究[J].南京理工大学学报(自然科学版),1998,(03):44.
　Lu Ming Lu Chunxu Wei Yunyang.A Study on the Condensation Reaction of 2,3-bishydroxylpiperazine with Some Amino compounds[J].Journal of Nanjing University of Science and Technology,1998,(02):44.
[4]李志平,魏运洋,吕春绪,等.二并哌嗪的合成与硝化研究[J].南京理工大学学报(自然科学版),1997,(03):245.
　Li Zhiping,Wei Yunyang,Lu Chunxu,et al.Study on the Synthesis and Nitration of Tetraazadecalin[J].Journal of Nanjing University of Science and Technology,1997,(02):245.
[5]芮久后,王泽山,刘玉海,等.超细黑索今制备新方法[J].南京理工大学学报(自然科学版),1996,(05):5.
　RuiJiuhou WangZeshan LiuYuhai ShiJie.A New Method for Preparation of Ultrafine RDX Crystals[J].Journal of Nanjing University of Science and Technology,1996,(02):5.
[6]王煊军,竹奇俊,王泽山.一种工业炸药爆速估算的新方法[J].南京理工大学学报(自然科学版),1996,(05):9.
　WangXuanjun ZhuQijun WangZeshan.A New Estimation Method of Detonation Velocity for Industrial Explosives[J].Journal of Nanjing University of Science and Technology,1996,(02):9.
[7]陆明,吕春绪,魏运洋.2，5，7，9－四硝基－2，5，7，9－四氮杂双环［4，3，0］壬－8－酮的合成及其性能[J].南京理工大学学报(自然科学版),1995,(04):325.
　Lu Ming,Lu Chunxu,Wei Yunyang.Synthesis and Property of 2,5,7,9-tetranitro-2,5,7,9-tetrazobicyclo[4,3,0]nonan - 8-one[J].Journal of Nanjing University of Science and Technology,1995,(02):325.
[8]李佩芳,夏红,念东,等.混合炸药中TNT与HNS的分离和测定[J].南京理工大学学报(自然科学版),1992,(01):54.
[9]陆明.六硝基联苄氧化成六硝基芪的研究[J].南京理工大学学报(自然科学版),1992,(04):48.
[10]李佩芳,夏爱军,陈辉,等.HPLC法测定火炸药厂废水中的苦味酸等七种炸药[J].南京理工大学学报(自然科学版),1990,(04):49.
　Li Peifang.Determination of PA,HMX,RDX,CE,TNT,PETN and DNT in Explosive Factory’s Wasted water by HPLC[J].Journal of Nanjing University of Science and Technology,1990,(02):49.

备注/Memo

备注/Memo:
国防科技预研行业基金
陆　明　男　34 岁　副教授
更新日期/Last Update: 2013-03-29