[1]韩巧凤,张江润,杨绪杰,等.三-(水杨醛乙醚基)胺缩丙二胺配合物的合成[J].南京理工大学学报(自然科学版),2002,(06):645-648.
 HanQiaofeng ZhangJiangrun YangXujie LuLude WangXin.Synthesis of Complexes of Tricsalicylal Ethyl Ether Amine Condensation with Propylenediamine[J].Journal of Nanjing University of Science and Technology,2002,(06):645-648.
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三-(水杨醛乙醚基)胺缩丙二胺配合物的合成()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
2002年06期
页码:
645-648
栏目:
出版日期:
2002-12-30

文章信息/Info

Title:
Synthesis of Complexes of Tricsalicylal Ethyl Ether Amine Condensation with Propylenediamine
作者:
韩巧凤张江润杨绪杰陆路德汪信
南京理工大学化工学院, 南京210094
Author(s):
HanQiaofeng ZhangJiangrun YangXujie LuLude WangXin
School of Chemical Engineering,NUST,Nanjing 210094
关键词:
席夫碱 大环配合物 缩合反应
Keywords:
Schif f base macrocyclic complex condensat ion react ion
分类号:
O641.4
摘要:
用丙二胺和三 - (水杨醛乙醚基 )胺 ,在无水甲醇中进行环缩合反应 ,生成了一个杂原子大环配体。并用该杂原子大环配体与过渡金属的盐进行置换反应 ,合成了相应金属 :Ni(Ⅱ )、Cu(Ⅱ )、Co(Ⅱ )、Zn(Ⅱ )和Cd(Ⅱ )的大环配合物。通过元素分析、FT -IR、NMR、UV和TG等谱学手段对配合物的结构及性质进行了表征和分析。结果表明 ,已合成得到了所需的大环配合物。
Abstract:
A new macrocyclic ligand w as synthesized by the condensat ion of 1, 3- propylenediamine and t ri( salicy lal ethyl ether) amine. The lig and w as used to prepare for a series of its transition metal complexes by the replacement react ion w ith metal salt s. T he macrocyclic complexes of Ni( Ⅱ) , Cu( Ⅱ) , Co (Ⅱ) , Zn( Ⅱ) and Cd( Ⅱ) w ere synthesized. The st ructures and propert ies of the complexes were characterized by EA, FT - IR, NMR, UV and TG. T he results show that macrocy lic complex es have been obtained.

参考文献/References:

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备注/Memo

备注/Memo:
韩巧凤 女 36 岁 讲师
更新日期/Last Update: 2002-12-30