[1]王 军,等.双(3-甲氧基-4-羟基)苯甲醛合氢氧化锌配合物的晶体结构[J].南京理工大学学报(自然科学版),2004,(03):303-306.
 WANG Jun,BEI Feng li,LI Ren yu,et al.Crystal Structure of Bis(3-methoxy-4-hydroxy) Benzaldehyde Dihydroxide Zinc(Ⅱ) Complex[J].Journal of Nanjing University of Science and Technology,2004,(03):303-306.
点击复制

双(3-甲氧基-4-羟基)苯甲醛合氢氧化锌配合物的晶体结构()
分享到:

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
2004年03期
页码:
303-306
栏目:
出版日期:
2004-06-30

文章信息/Info

Title:
Crystal Structure of Bis(3-methoxy-4-hydroxy) Benzaldehyde Dihydroxide Zinc(Ⅱ) Complex
作者:
王 军1 2 卑凤利1 李人宇1 杨绪杰1 陆路德1 汪 信1
1. 南京理工大学化工学院, 江苏南京210094; 2. 江苏警官学院科技系, 江苏南京210012
Author(s):
WANG Jun 12 BEI Feng li 1LI Ren yu 1YANG Xu jieLU Lu de 1WANG Xin 1
1.School of Chemical Engineering,NUST,Nanjing 210094,China;2.Department of Police Technique, Jiangsu Police Institude , Nanjing, 210012,China
关键词:
Zn 配合物 单晶 双( 3- 甲氧基- 4- 羟基) 苯甲醛
Keywords:
zinc( Ⅱ ) complex crystal st ructure bis( 3- methox y- 4- hydroxy) benzaldehy
分类号:
O641.4
摘要:
合成双 ( 3-甲氧基 - 4-羟基 )苯甲醛合氢氧化锌配合物 ,测定红外光谱、热重、单晶结构 ,晶体C16H18O8Zn属单斜晶系 ,空间群为Cc ,晶胞参数 :a =2 .2 1 6 7( 4 )nm ,b =1 .0 540 ( 2 )nm ,c =0 .780 0 ( 2 )nm ,β =1 0 6 .9°,Z =4。结构解析最终一致性因子R1=0 .0 390 ,wR2 =0 .0 91 6。中心Zn原子通过 6个O原子形成八面体结构的配合物。分子间通过氢键和范德华力形成 3D网状超分子结构。
Abstract:
Bis ( 3- methox y- 4 - hydrox y) benzaldehyde dihydrox ide zinc( Ⅱ ) complex has been synthesized and characterized by IR and single-crystal X- ray analysis. The crystal is monoclinic, space g roup Cc w ith a = 2. 216 7( 4) nm, b = 1. 054 0( 2) nm, c = 0. 780 0( 2) nm, B= 106. 92( 3)°, Z = 4, R 1 = 0. 039 0, w R 2 = 0. 091 6 . The cent ral zinc atom is octahedrally coordinated by an arrangement of six O atoms. In the crystal latt ice, the molecules form a three-dimension netw ork st ructure throug h hydrogen bonds. The C ) H ,O intermolecular hydrogen bonds and van der w aals interact ion connect the t itle complex to form net supermolecular st ructure.

参考文献/References:

[ 1] Kumar C V, Emma H A. DNA binding studies and site select ive fluorescence sensitization of an anthry pr obe[ J] . J Am Chem Soc, 1993, 115( 19) : 8 547~ 8 553.
[ 2] Morrow J R, Kolosa K. Cleavage of DNA by nickel complex es[ J] . Inorg Chim Acta, 1992, 195: 245~ 248.
[ 3] Angel G R, Juan J F, Adela L Z, et al. Synthesis of Zn N- salicylidene- L- aminoacidatos: X- ray structure of [ ( N- salicylidene- L- alaninato) ( aqua ) zinc ( Ò ) ] ·0. 25H2O and [ ( N- salicylidene- L- alaninato ) ( aqua ) zinc ( Ò) ] [ J] . Po lyheder on, 2000, 19: 673~ 680.
[ 4] Lu Qin, Sheng Chengyu, Luo Qinhui. A study on the schiff base Cu2Zn2- SOD mo del complex es ) The relationship between structure and activ ity[ J] . Poly hedro n, 1993, 12( 16) : 2 005~ 2 008.
[ 5] Lu Q, Luo Q H, Dai A B, et al. The synthesis and crystal structure of imidazolate- br idg ed [ Cu( tren) ( im) Zn( tren) ] ( ClO4) 3·MeOH[ J] . J Chem Soc, Chemical Communicacations, 1990, 20: 1 429~ 1 430.
[ 6] Luo Qinhui, Zheng Limin, Lu Qin, et al. Synthesis, crystal structur e and properties of [ Cu( tren) ( im) Zn ( tren) ] ( ClO4) 3·CH3OH as a model compound of BESOD[ J] . Sci in China ( Series B) , 1993, 36( 2) : 170.
[ 7] Sheldrick G M. In computational crystallography[ M] . Sayr e D. New York: Ox ford Univ ersity Press, 1982. 506~ 514.
[ 8] Lide D R. CRC handbook of chemistry and physics[M] . 73rd Edition. Boca Rato n: CRC, 1993. 98.

相似文献/References:

[1]鲁娟,韩巧风,杨绪杰,等.仲丁氧基二硫代甲酸铜与三苯基膦配合物[J].南京理工大学学报(自然科学版),2005,(02):223.
 LU Juan,HAN Qiao-feng,YANG Xu-jie,et al.Complex of (O-sec.-Butyldithiocarbonatio-S,S’) Copper (Ⅰ) and Triphenylphosphine[J].Journal of Nanjing University of Science and Technology,2005,(03):223.

备注/Memo

备注/Memo:
作者简介: 王 军( 1969- ) , 男, 江苏仪征人, 博士生, 主要研究方向: 配位化学, E-mail: kwang jun@ 163. com。
更新日期/Last Update: 2013-03-11