[1]韩巧凤,马卫华,罗元香,等.环己基黄原酸铜与菲咯啉配合物的结构[J].南京理工大学学报(自然科学版),2004,(03):307-310.
 HAN Qiao feng,MA Wei hua,LUO Yuan xiang,et al.The Structure of Bis(O-cyclohexyldithiocarbonatio-S,S’) (1,10-phenanthroline-N1,N10) Copper(Ⅱ) Complex[J].Journal of Nanjing University of Science and Technology,2004,(03):307-310.
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环己基黄原酸铜与菲咯啉配合物的结构()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
2004年03期
页码:
307-310
栏目:
出版日期:
2004-06-30

文章信息/Info

Title:
The Structure of Bis(O-cyclohexyldithiocarbonatio-S,S’) (1,10-phenanthroline-N1,N10) Copper(Ⅱ) Complex
作者:
韩巧凤马卫华罗元香杨绪杰汪信
南京理工大学化工学院, 江苏南京210094
Author(s):
HAN Qiao fengMA Wei huaLUO Yuan xiangYANG Xu jieWANG Xin
School of Chemical Engineering,NUST,Nanjing 210094,China
关键词:
黄原酸盐 1 10- 菲咯啉 晶体结构
Keywords:
xanthate 1 10-phenanthroline crystal st ructure
分类号:
O641.4
摘要:
合成了环己基黄原酸铜及其与 1 ,1 0 -菲咯啉的配合物 [Cu(C6H11OCSS) 2(phen) ],通过单晶X-射线衍射测定得到了该配合物的晶体结构。该晶体属单斜晶系 ,空间群为P2 1/c ,晶胞参数a =1 .2 2 80 ( 3)nm ,b =1 .86 1 0 ( 4 )nm ,c=1 .2 86 0 ( 3)nm ,β=1 0 4 .50 ( 3)° ,V =2 .84 53( 1 0 )nm3 ,Z=4。铜原子为六配位 ,分别与一个菲咯啉分子的 2个氮原子及 2个环己基黄原酸根的 4个硫原子配位红外及紫外可见光谱分析结果与晶体结构一致。
Abstract:
The t it le compound, [ Cu( phen) ( C6H11OCSS) 2] is synthesized and its crystal st ructure is determined by X- ray diff ract ion. The crystal is monoclinic of space g roup P 21/ c , w ith parameters a = 1. 228 0( 3) nm, b = 1. 861 0( 4) nm, c = 1. 286 0( 3) , B= 104. 50( 3) , V = 21845 3( 10) nm3 and Z = 4. Cu atom is six-coordinated by two nit rogen atoms from phenanthroline ligand and four sulfur atoms from tw o ( O-cy clohex yldithiocarbonatio) anions. The inf ra red and ult raviolet-visible spectroscopic results supported the crystal structure.

参考文献/References:

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备注/Memo

备注/Memo:
作者简介: 韩巧凤( 1966- ) , 女, 江苏武进人, 副教授, 主要研究方向: 材料化学, E-mail: hanqiaofeng@tom. como 。
更新日期/Last Update: 2013-03-11