[1]马建旗,卑凤利,李俊琦,等.二异丙基二硫代氨基甲酸钼配合物的室温固相合成、表征及晶体结构[J].南京理工大学学报(自然科学版),2004,(06):648-652.
 MA Jian-qi,BEI Feng-li,LI Jun-qi,et al.Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum[J].Journal of Nanjing University of Science and Technology,2004,(06):648-652.
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二异丙基二硫代氨基甲酸钼配合物的室温固相合成、表征及晶体结构()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
2004年06期
页码:
648-652
栏目:
出版日期:
2004-12-30

文章信息/Info

Title:
Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum
作者:
马建旗卑凤利李俊琦杨绪杰陆路德汪信
南京理工大学材料化学实验室, 江苏南京210094
Author(s):
MA Jian-qiBEI Feng-liLI Jun-qiYANG Xu-jie LU Lu-deWANG Xin
Materials Chemistry Laboratory, NUST, Nanjing 210094,China
关键词:
二异丙基二硫代氨基甲酸钼 室温固相反应 晶体结构
Keywords:
bis( diiso- propylcarbamodithioato- S S’ ) Molybdenum solid phase reaction at room temperature crystal structure
分类号:
O627;O641.4
摘要:
磷钼酸与二异丙基二硫代氨基甲酸钠通过室温固相反应 ,合成了二异丙基二硫代氨基甲酸合钼 ,用红外光谱、X 射线粉末衍射谱和TG -DTA ,对产物进行了表征 ,并且测定其单晶结构。标题化合物属单斜晶系 ,P2 1/c空间群 ,晶胞参数a=0 .81 570 ( 1 6 )nm ,b=1 .784 4( 4 )nm ,c=1 .56 48( 5)nm ,β=1 1 0 .38( 3)°,V =2 .1 351 ( 9)nm3 ,Z=4 ,Dc =1 .396Mg/m3 ,F( 0 0 0 ) =92 8,μ
Abstract:
Bis( diiso-propylcarbamodithioato- S, S ) Molybdenum was synthesized by the solid phase react ion of phosphomolybdic acid and diiso-propylcarbamodithioato sodium at room temperature. The product was characterized by IR, Xray powder diffract ion and TG- DTA. Its single crystal was deter mined by X ray single crystal diffraction. The crystal belongs to monoclinic system with a space group P21/ c, a = 0. 815 70( 16) nm, b = 1. 784 4( 4) nm, c = 1. 564 8( 5) nm, β= 110. 38( 3), V = 2. 135 1( 9) nm 3 , Z = 4, Dc = 1. 396 Mg/ m 3 , F( 000) = 928, μ= 1. 002 mm - 1 , R = 0. 088 8, Rw = 0. 144 2, GOF = 1. 092.

参考文献/References:

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备注/Memo

备注/Memo:
基金项目: 国家自然科学基金( 50372028)
作者简介: 马建旗( 1978- ) , 男, 河北唐县人, 硕士, 主要研究方向: 配合物的结构与性能表征, E-mail:zhonghua555@163. com; 通讯作者: 汪信( 1948- ) , 男, 江苏常州人, 教授, 博士生导师, 主要研究方向:纳米材料, E-mail: wxin@ publicl。
更新日期/Last Update: 2013-03-11