[1]王瑛,纪明中,严莲荷.十四烷基二甲基苄基氯化铵的合成及晶体结构[J].南京理工大学学报(自然科学版),2005,(05):90-93.
 WANG Ying,JI Ming-zhong,YAN Lian-he.Crystal Structure and Characterization of Tetradecyl Dimethyl Benzyl Ammonium Chloride C23H42ClN·2H2O[J].Journal of Nanjing University of Science and Technology,2005,(05):90-93.
点击复制

十四烷基二甲基苄基氯化铵的合成及晶体结构
分享到:

《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
2005年05期
页码:
90-93
栏目:
出版日期:
2005-10-30

文章信息/Info

Title:
Crystal Structure and Characterization of Tetradecyl Dimethyl Benzyl Ammonium Chloride C23H42ClN·2H2O
作者:
王瑛纪明中严莲荷
南京理工大学化工学院, 江苏南京210094
Author(s):
WANG YingJI Ming-zhongYAN Lian-he
School of Chemical Engineering,NUST,Nanjing 210094,China
关键词:
合成 晶体结构 正交晶系
Keywords:
synthesis crystal structure orthorhombic
分类号:
O625.6;
摘要:
合成了标题化合物C23H42ClN.2H2O(CCDC No:227826),得到无色柱状晶体。晶体属正交晶系,空间群为P21/c,晶胞参数a=2.0510(4)nm,b=1.1720(2)nm,c=1.0800(2)nm,V=2.5959(9)nm3,Mr=404.06,Z=4,Dc=1.034 g/cm3,F(000)=896,R=0.0590,wR=0.1789。4个C—N键的键长范围在0.1498(4)~0.1535(4)nm,热分析表明标题化合物在370.6℃完全分解。
Abstract:
The title compound ( CCDC No: 227826) is prepared and characterized by elemental analysis, infrared spectra and thermal analysis. The crystal structure of tetradecyl dimethyl benzyl ammonium chloride C23H42ClN·2H2O is determined by X-ray diffraction method. The compound crystallizes in orthorhombic system, space group P21/ c , with latt ice parameters a = 2. 0510( 4) nm, b = 1. 1720( 2) nm, c = 1. 0800( 2) nm, Mr = 404. 06, V = 2. 5959( 9) nm3, Z = 4, Dc = 1. 034 g/ cm3, F ( 000) = 896, R = 0. 0590 and wR = 0. 1789. The four C- N bond distances are in the range of 0. 1498( 4) - 0. 1535( 4) nm. The IR spectral data are in agreement with the structural data. The thermal analytical data indicate that the compound is decomposed completely at the temperature of 370. 6 ℃.

参考文献/References:

[ 1] 何铁林. 水处理化学品手册[M] . 北京: 化学工业出版社, 2001. 280.
[ 2] 周本省. 工业水处理技术[M] . 北京: 化学工业出版社, 2000. 122.
[ 3] 郭东红, 王玉洁, 蔡永生, 等. 新型高效原油破乳剂 PNT- 05 的研制与应用[ J] . 化学通报, 2001, 64( 4) : 240 ~ 243.
[ 4] 中国石油化工总公司. 冷却水分析和实验方法[M] . 北京: 中国石化出版社, 1993.
[ 5] Sheldrick G M. SADABS, program for empirical absorption correction of area detector data [M] . Germany: University of Gottingen, 1996.
[ 6] Sheldrick G M. SHELXTL ( Version 5. 10) [ R] . Madison, Wisconsin, USA: Analytical X- ray Instruments Inc, 1997.
[ 7] Wilson A J. International tables for X- ray crystallography( Vol C) [M] . Dordrecht: Kluwer Academic Publishers, 1992. 500- 502; 219- 222.
[ 8] Wang Y, Jian F F, Lu L D, et al. Diphenylcarbazide acetonitrile solvat [ J] . Acta Crystallographica ( Sect E) , 2001, E57, O313.
[ 9] 王瑛, 严莲荷, 程媛. 吗啉二硫代氨基甲酸铁配合物的合成及晶体结构[ J] . 有机化学, 2003, 23: 690- 694.
[ 10] Xiong R G, Liu C M, Zuo J L, et al. A novel molecular channel:Thermal analyses and X- ray structure of [ Ni( Et - XA) 2?phen] ? 3H2O[ J] . Polyhedron, 1997, 16: 2 315 - 2 317.
[ 11] 吴瑾光. 近代傅立叶变换红外光谱技术及应用[M] . 北京: 科学技术文献出版社, 1994. 605.

相似文献/References:

[1]韩巧凤,马卫华,罗元香,等.环己基黄原酸铜与菲咯啉配合物的结构[J].南京理工大学学报(自然科学版),2004,(03):307.
 HAN Qiao feng,MA Wei hua,LUO Yuan xiang,et al.The Structure of Bis(O-cyclohexyldithiocarbonatio-S,S’) (1,10-phenanthroline-N1,N10) Copper(Ⅱ) Complex[J].Journal of Nanjing University of Science and Technology,2004,(05):307.
[2]马建旗,卑凤利,李俊琦,等.二异丙基二硫代氨基甲酸钼配合物的室温固相合成、表征及晶体结构[J].南京理工大学学报(自然科学版),2004,(06):648.
 MA Jian-qi,BEI Feng-li,LI Jun-qi,et al.Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum[J].Journal of Nanjing University of Science and Technology,2004,(05):648.
[3]蔡敏敏,陈天云,黄建祯,等.无机盐添加剂对硝酸铵晶变及结块性的影响[J].南京理工大学学报(自然科学版),2000,(01):76.
 CaiMinmin ChenTianyun HuangJianzhen LuChunxu.Effect of Inorganic Additives on AN Polymorphism and Caking[J].Journal of Nanjing University of Science and Technology,2000,(05):76.
[4]吴幼成.迭氮化铅的自爆现象及其产生的原因[J].南京理工大学学报(自然科学版),1982,(02):89.
[5]胡永红,毛彩霞.含氧空位ZnO压强依赖的晶体结构和光电性质[J].南京理工大学学报(自然科学版),2015,39(06):763.
 Hu Yonghong,Mao Caixia.Pressure-dependent crystal structure and optoeletronic properties of ZnO containing O vacancy[J].Journal of Nanjing University of Science and Technology,2015,39(05):763.
[6]黄秋颖,刘春丽,孟祥茹.二维层状镉配合物的合成、结构及性能[J].南京理工大学学报(自然科学版),2017,41(01):108.[doi:10.14177/j.cnki.32-1397n.2017.41.01.015]
 Huang Qiuying,Liu Chunli,Meng Xiangru.Synthesis,structure and properties of two-dimensionallayered Cd(Ⅱ)complex[J].Journal of Nanjing University of Science and Technology,2017,41(05):108.[doi:10.14177/j.cnki.32-1397n.2017.41.01.015]
[7]黄秋颖,林肖漪,孟祥茹.二维锌配合物的合成、结构及性能研究[J].南京理工大学学报(自然科学版),2017,41(02):232.[doi:10.14177/j.cnki.32-1397n.2017.41.02.015]
 Huang Qiuying,Lin Xiaoyi,Meng Xiangru.Synthesis,structure and property of 2D znic complex[J].Journal of Nanjing University of Science and Technology,2017,41(05):232.[doi:10.14177/j.cnki.32-1397n.2017.41.02.015]
[8]黄秋颖,江金永,李姗珊,等.基于氮杂环和羧酸配体的银(I)配合物的合成、结构及性能[J].南京理工大学学报(自然科学版),2017,41(04):533.[doi:10.14177/j.cnki.32-1397n.2017.41.04.020]
 Huang Qiuying,Jiang Jinyong,Li Shanshan,et al.Synthesis,structure and properties of a Ag(I)complex based onN-heterocyclic and carboxylic acid ligands[J].Journal of Nanjing University of Science and Technology,2017,41(05):533.[doi:10.14177/j.cnki.32-1397n.2017.41.04.020]
[9]赵 扬,李林蔚,赵丹丹,等.基于氮杂环羧酸配体的镍(II)配合物的合成、结构及性能研究[J].南京理工大学学报(自然科学版),2018,42(01):114.[doi:10.14177/j.cnki.32-1397n.2018.42.01.017]
 Zhao Yang,Li Linwei,Zhao Dandan,et al.Synthesis,structure and properties of Ni(II)complexbased on N-heterocyclic carboxylate ligand[J].Journal of Nanjing University of Science and Technology,2018,42(05):114.[doi:10.14177/j.cnki.32-1397n.2018.42.01.017]
[10]刘春丽,冯俊阳,岳志芳,等.咪唑二羧酸基二维钴配位聚合物的晶体结构及性能[J].南京理工大学学报(自然科学版),2018,42(04):491.[doi:10.14177/j.cnki.32-1397n.2018.42.04.015]
 Liu Chunli,Feng Junyang,Yue Zhifang,et al.Crystal structure and properties of imidazole dicarboxylate-based2D Co(Ⅱ)coordination polymer[J].Journal of Nanjing University of Science and Technology,2018,42(05):491.[doi:10.14177/j.cnki.32-1397n.2018.42.04.015]

备注/Memo

备注/Memo:
江苏省社会发展基金(BS2002043)
作者简介: 王瑛( 1965- ) , 女, 河北承德人, 副研究员, 硕士, 主要研究方向: 水处理药剂合成; E-mail: wangying7012003@yahoo. com. cn。
更新日期/Last Update: 2013-05-29