[1]张 防,等.1,4-苯二甲酸镉的合成及其热分解制备CdO纳米晶[J].南京理工大学学报(自然科学版),2009,(01):137-141.
 ZHANG Fang,BEI Feng-li,LIU Xiao-heng,et al.Preparation of Nano-sized Crystal CdO by Thermal Decomposition of Cadmium Complex of 1,4-Benzene Dicarboxylic Acid[J].Journal of Nanjing University of Science and Technology,2009,(01):137-141.
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1,4-苯二甲酸镉的合成及其热分解制备CdO纳米晶
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
2009年01期
页码:
137-141
栏目:
出版日期:
2009-02-28

文章信息/Info

Title:
Preparation of Nano-sized Crystal CdO by Thermal Decomposition of Cadmium Complex of 1,4-Benzene Dicarboxylic Acid
作者:
张 防1 2 卑凤利1 刘孝恒1 汪 信1
1. 南京理工大学化工学院, 江苏南京210094; 2. 南京航空航天大学材料科学与技术学院, 江苏南京210016
Author(s):
ZHANG Fang12BEI Feng-li1LIU Xiao-heng1WANG Xin1
1.School of Chemical Engineering,NUST,Nanjing 210094,China;2.College of Materials Science and Technology,Nanjing University of Aeronautics and Astronautcs,Nanjing 210016,China
关键词:
14-苯二甲酸 配合物 纳米晶 氧化镉
Keywords:
14-benzene dicarboxylic acid complex nano-sized crystals CdO
分类号:
TB383.1
摘要:
采用液相分散沉淀法在常温下制备了1,4-苯二甲酸镉配合物,分别利用元素分析、热分析、红外光谱以及X射线衍射对配合物进行了表征。利用X射线衍射研究了配合物在高温下的焙烧过程,并利用红外光谱、荧光光谱以及透射电子显微镜对焙烧产物进行了表征。结果表明,将配合物在高温下焙烧可得到CdO纳米晶,晶粒平均尺寸为20~30 nm。
Abstract:
Cadmium complex of 1,4-benzene dicarboxylic acid is synthesized by liquid dispersion deposition method at normal temperature and the complex is characterized by element analysis,thermal analysis,infrared spectrum and X-ray diffraction,respectively.The calcining process of complex at high temperature is investigated by X-ray diffraction and the calcinated products are characterized by infrared spectrum,fluorescence spectrum and transmission electron microscopy.The results show that nano-sized CdO crystals with average size of 20~30 nm can be obtained by calcining complex precursors at higher temperature.

参考文献/References:

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备注/Memo

备注/Memo:
基金项目: 国家自然科学基金( 50572039); 江苏省自然科学基金( BK2005130)
作者简介: 张防( 1974 - ), 男, 博士生, 主要研究方向: 纳米结构材料的控制合成, E-m ail:zhangfang@ nuaa.edu. cn。
更新日期/Last Update: 2012-11-19