[1]樊慧明,孟凡娜,刘建安,等.基于Minitab的苯丙乳液合成影响因素分析及方案优化[J].南京理工大学学报(自然科学版),2012,36(02):369-374.
 FAN Hui-ming,MENG Fan-na,LIU Jian-an.Influence Factors and Scheme Optimization of Styrene-Acrylate Copolymer Emulsion Synthesis By Minitab[J].Journal of Nanjing University of Science and Technology,2012,36(02):369-374.
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基于Minitab的苯丙乳液合成影响因素分析及方案优化
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
36卷
期数:
2012年02期
页码:
369-374
栏目:
出版日期:
2012-04-30

文章信息/Info

Title:
Influence Factors and Scheme Optimization of Styrene-Acrylate Copolymer Emulsion Synthesis By Minitab
作者:
樊慧明; 孟凡娜; 刘建安;
华南理工大学制浆造纸国家重点实验室; 华南理工大学造纸与污染控制国家工程研究中心;
Author(s):
FAN Hui-ming12MENG Fan-na12LIU Jian-an12
1.Pulp and Paper Engineering State Key Laboratory;2.National Engineering Research Center of Papermaking and Pollution Control,South China University of Technology,Guangzhou 510640,China
关键词:
Minitab Plackett-Burman设计 Box-Benhnken设计 响应优化器 苯丙乳液 表面施胶
Keywords:
Minitab Plackett-Burman design Box-Benhnken design response optimizers styrene-acrylate copolymer emulsion surface sizing
分类号:
TS727.5
摘要:
该文利用Minitab软件中的Plackett-Burman、Box-Benhnken和响应优化器设计和优化苯丙乳液合成实验,综合分析了影响苯丙乳液合成的因素,获得了较优的合成方案。首先利用Plackett-Burman设计实验方案并分析实验数据,筛选出影响苯丙乳液合成的3个主要因素:乳化剂用量、功能单体用量、引发剂用量。然后利用Box-Benhnken设计实验,用响应优化器优化实验结果得到较优的合成方案:苯乙烯和丙烯酸酯单体的质量配比为1∶1,转速220 r/min,反应温度75℃,乳化剂、功能单体和引发剂质量分数分别为1.04%,1.85%,0.47%。用合成的苯丙乳液与阴离子淀粉配制成表面施胶液施胶复印纸原纸,施胶纸张平均Cobb值达22.6 g/m2。实验结果表明,与其他合成方案相比,用Minitab优化方案合成的苯丙乳液施胶效果最好,其各项性能的预测值与实验平均值拟合度达98.26%~98.72%。
Abstract:
By using the Plackett-Burman design,the Box-Benhnken design and the response optimizer in the Minitab software to design and optimize the styrene-acrylate emulsion synthesis experiments,the influence factors on the synthesis are analyzed and the optimal synthesis scheme is obtained.The Plackett-Burman is applied to conduct the experiment.By analyzing the experimental data,the dosages of emulsifiers,initiators and functional monomers are obtained as the three main influence factors on the styrene-acrylate copolymer emulsion performance.The Box-Benhnken is used to design the experiment and the experimental data are optimized by the response optimizer to get the optimal synthesis scheme:the monomer mass ratio of styrene to butyl acrylic is 1∶1,the rotate speed is 220 r/min,the reaction temperature is 75 ℃,and the mass percentages of emulsifiers,functional monomers and initiators are 1.04%,1.85% and 0.47% respectively.The synthetized styrene-acrylate emulsion is mixed with the anionic starch as surface sizing agent to size the copy base pape,and the average Cobb value of sized paper is 22.6 g/m2.The experimental results show that styrene-acrylate copolymer emulsion synthesized under the Minitab optimized scheme gives the best sizing efficiency,and the agreement of the average experimental results and the predicted value for performances reaches 98.26%~98.72%.

参考文献/References:

[1] 杨铭. Minitab 用于中心复合设计与数据处理[J].药学服务与研究, 2007,7 ( 3) : 231-234.
[2] Taddei A,Rodríguez M J,Márquez-Vilchez E, et al. Isolation and identification of Streptomyces spp. from Venezuelan soils: Morphological and biochemical studies. I. [J]. Microbiological Research,2006,161 ( 3) : 222-231.
[3] Antony J. 9-Case studies[J]. Design of Experiments for Engineers and Scientists, 2003: 105-148.
[4] 马小魁,陈五岭,陈勇. 利用Minitab 软件优化酵母培养基[J]. 食品与发酵工业, 2005, 31( 12) : 72-75.
[5] Febe F,Abdulhameed S,Nampoothiri K M. Use of response surface methodology for optimizing process parameters for the production of α-amylase by aspergillus oryzae[J]. Biochemical Engineering Journal,2003,15 ( 2) : 107-115.
[6] Fan Y T,Li C L,Lay J J,et al. Optimization of initial substrate and PH levels for germination of sporing hydrogen- producing anaerobes in cow dung compost[J]. Bioresour Technol, 2004, 91( 2) : 189-193.
[7] Osman M I. Exploring a mixture of distributions using minitab [J]. Computers in Biology and Medicine, 1997, 23( 3) : 223-232.
[8] 王春荣,纪春暖,王海燕,等. Minitab 15. 0 软件在制备酚醛树脂型聚合物微球中的应用[J]. 鲁东大学学报( 自然科学版) , 2009, 25( 3) : 242-245.
[9] 蔡春,罗桂琴,吕春绪. 甲苯的硝酸-离子交换树脂硝化及动力学研究[J]. 华东工学院学报,1991,15 ( 4) : 39-44.
[10] 戴振东,Stanislav G. 聚氨酯粘着性能的实验研究[J]. 南京理工大学学报, 2004, 28( 1) : 38-56.
[11] 卢谦和. 造纸原理与工程[M]. 第2 版. 北京: 中国轻工业出版社, 2004.
[12] 沈一丁. 造纸化学品的制备和作用机理[M]. 北京: 中国轻工业出版社, 1999.
[13] Beres D L,Hawkins D M. Plackett-Burman technique for sensitivity analysis of many-parametered models [J]. 河南农业科学, 2001, 141( 1-3) : 171-183.[14] 王建高,樊慧明,刘建安,等. 初始pH 对无皂苯丙乳液表面施胶剂性能的影响[J]. 造纸化学品,2010, 22( 2) : 1-4.
[15] Yang S F,Xiong P T,Gong T,et al. St-BA copolymer emulsions prepared by using novel cationic maleic dialkyl polymerizable emulsifier[J]. European Polymer Journal, 2005, 41( 12) : 2973-2979.
[16] 黄杰,曾幸荣,李红强,等. 单体及乳化剂组成对核壳型丙烯酸酯乳液性能的影响[J]. 精细石油化工, 2010, 27( 1) : 31-35.
[17] 罗付生,丁建东,李凤生. 聚苯乙烯微球包覆TiO2 粉体改性研究[J]. 南京理工大学学报,2002,26 ( 3) : 312-315.
[18] 朱殿奎,周天寿,汪信,等. 室温自交联型TF 弹性防水涂料性能研究[J]. 南京理工大学学报,2005,29 ( 2) : 219-222.
[19] 孙志娟,张心亚,江庆梅,等. 乳化剂对半连续乳液聚合动力学及成核机理的影响[J]. 华南理工大学学报( 自然科学版) , 2007, 35( 5) : 126-131.
[20] Starov V M,Zhdanov V G. Viscosity of emulsions: influence of flocculation[J]. Journal of Colloid and Interface Science, 2003, 258( 2) : 404-414.
[21] Benjamins J,Vingerhoeds M H,Zoet F D, et al. Partial coalescence as a tool to control sensory perception of emulsions [J]. Food Hydrocolloids,2009,23 ( 1 ) : 102 -115.
[22] 李晓宣,李星纬,蒋鹏举. 乙二醛/尿素树脂的合成及在造纸上的应用[J]. 南京理工大学学报,1999, 23( 2) : 162-165.
[23] 李翾,沈一丁,费贵强,等. 自交联苯丙乳液的无皂聚合及其结构与表面施胶性能[J]. 中国造纸学报, 2009, 24( 1) : 100-103.
[24] Alam M Z,Suleyman A M,Wahid R. Statistical optimization of process conditions for cellulase production by liquid state bioconversion of domestic wastewater sludge[J]. Bioresource Technology,2008,99 ( 11 ) : 4709-4716.
[25] Francis F,Sabu A,Nampoothiri K M,et al. Use of response surface methodology for optimizing process parameters for the production of α-amylase by Aspergillus oryzae[J]. Biochemical Engineering Journal,2003,15 ( 2) : 107-115.
[26] Li C,Bai J H,Cai Z L, et al. Optimization of a cultural medium for bacteriocin production by Lactococcus lactis using response surface methodology[J]. Journal of Biotechnology, 2002, 93( 1) : 27-34.
[27] Warson H,Finch C A. Application of Synthetic Resin Latices,Volume 1: Fundamental Chemistry of Latices and Application in Adhesives[M]. London: John Wiley and Sons, 2004: 143-151.
[28] Ai Z Q,Deng R,Zhou Q L, et al. High solid content latex: Preparation methods and application[J]. Colloid and Interface Science, 2010, 159( 1) : 45-49.[29] Guyot A,Chu F,Schneider M, et al. High solid content latexes[J]. Polymer Science, 2002, 27( 8) : 1573-1615.

备注/Memo

备注/Memo:
广东省科技计划项目(2008B080202002;2011B010300015)
更新日期/Last Update: 2012-10-12