[1]石立安,麻海燕,柯凯,等.混凝土的抗酸雨腐蚀性及其机理研究[J].南京理工大学学报(自然科学版),2012,36(04):717-723.
　SHI Li-an,MA Hai-yan,KE Kai.Concrete ’ s Resistance to Acide Rain and Its Mechanism[J].Journal of Nanjing University of Science and Technology,2012,36(04):717-723.
点击复制

混凝土的抗酸雨腐蚀性及其机理研究
分享到：

《南京理工大学学报》（自然科学版）[ISSN:1005-9830/CN:32-1397/N]

卷:
36卷
期数:
2012年04期
页码:
717-723
栏目:
出版日期:
2012-08-31

文章信息/Info

Title:
Concrete ’ s Resistance to Acide Rain and Its Mechanism
作者:
石立安； 麻海燕； 柯凯；
南京航空航天大学土木工程系； 浙江建设职业技术学院建筑工程系； 武汉理工大学材料科学与工程学院；
Author(s):
SHI Li-an1; 2; MA Hai-yan1; KE Kai3
1.Department of Civil Engineering,Nanjing University of Aeronautics & Astronautics,Nanjing 210016,China; 2.Department of Building Engineering,Zhejiang College of Construction,Hangzhou 311231,China; 3.School of Material Science and Engineering,Wuhan Univer
关键词:
酸雨;  聚丙烯纤维;  孔结构;  水化产物
Keywords:
acid rain;  polypropylene fibers;  pore structures;  hydration products
分类号:
TU528
摘要:
为了考察混凝土建筑在酸雨环境腐蚀下的耐久性问题,研究不同配合比的混凝土材料在酸雨侵蚀作用下的抗压强度、抗折强度和抗冲击性等性能,通过X射线衍射(XRD)、压汞测孔法(MIP)、扫描电镜和能谱仪(SEM-EDS)等测试方法,从粉煤灰、膨胀剂、聚丙烯纤维的作用机理入手,研究了侵蚀前后混凝土试块中水化产物微观结构及内部孔结构特征的变化。结果表明,聚丙烯纤维粉煤灰膨胀混凝土的抗酸雨腐蚀性效果最佳。基准混凝土水化产物在酸雨介质侵蚀下易转换为石膏和SiO2.nH2O,而聚丙烯纤维粉煤灰膨胀混凝土结构致密,有害孔显著减少,可有效阻碍酸雨介质侵蚀作用。
Abstract:
In order to evaluate the durability of concrete constructions exposed to acid rain,such properties of concrete corroded by acid rain are investigated here as compressive strength,flexural strength and resistance to impact.By means of X ray diffraction(XRD),mercury intrusion poremeasurement(MIP),scanning electron microscope(SEM)and energy dispersive spectrometer(EDS),mechanism of fly ash,expansive agent and polypropylene fiber are investigated.Microstructure and porosity characteristics of hydrated products before and after corrosion are also examined.The results indicate that the polypropylene fiber reinforced concrete incorporated with fly ash and expansion agent exhibit better anti acid rain corrosion performance than other mixes.The hydration products of the reference sample are easily converted to gypsum and SiO2·nH2O under the action of acid rain.Microstructure of concrete adding admixture is denser so as to effectively prevent concrete damage induced by acid rain.

参考文献/References:

［1］ 范进，董福兴． 疲劳荷载下钢筋锈蚀混凝土构件粘结性能试验研究［J］． 南京理工大学学报，2009，33 ( 6) : 734－737．
Fan Jin，Dong Fuxing． Bond-slip fatigue experimental study on corroded reinforcement concrete members under cyclic loading［J］． Journal of Nanjing University of Science and Technology， 2009， 33( 6) : 734－737．
［2］ 钱桂枫，高祥彪，钱春香． PVA 纤维对混凝土力学性能的影响［J］． 混凝土与水泥制品，2010，6 ( 3) : 52 －54．
Qian Guifeng，Gao Xiangbiao，Qian Chunxiang． Effect on mechanical properties of PVA fiber reinforced strength concrete ［J］． China Concrete and Cement Products， 2010，6 ( 3) : 52－54．
［3］ 郑文忠，赵军卫，张博一． 活性粉末混凝土局压承载力试验与分析［J］． 南京理工大学学报，2008，32 ( 3) : 381－386．
Zheng Wenzhong， Zhao Junwei， Zhang Boyi． Experiment and analysis of local compression bearing capacity of reactive powder concrete［J］． Journal of Nanjing University of Science and Technology，2008， 32( 3) : 381－386．
［4］ Sakr K． Effect of cement type on the corrosion of reinforcing steel bars exposed to acidic media using electrochemica1 techniques［J］． Cement and ConcreteResearch， 2005， 35( 9) : 1820－1826
［5］ Malek R I． The contribution of class-F fly ash to the strength of cementitious mixtures［J］． Cement and Concrete Research， 200535( 2) : 1152－1154．
［6］ 李响，阎培渝． 粉煤灰掺量对水泥孔溶液碱度与微观结构的影响［J］． 建筑材料学报， 2010， 26( 6) : 787 －791．
Li Xiang，Yan Peiyu． Influence of fly ash content on alkalinity of pore solution and microstructure of cement pastes［J］． Journal of Builiding Materials，2010，26 ( 6) : 787－791．
［7］ 本斯迪德J． 水泥的结构与性能［M］． 廖欣，译． 北京: 化学工业出版社， 2008: 592－595．
［8］ 阎培渝． 复合胶凝材料水化过程中Ca( OH) 2 量的变化［J］． 建筑材料学报， 2010， 13( 5) : 564－567．
Yan Peiyu． Alteration of Ca( OH) 2 content during hydration process of composite binders［J］． Journal of Builiding Materials， 2010 13( 5) : 564－567．
［9］ 张士萍，邓敏，吴建华，等． 某机场道肩混凝土损伤原因分析［J］． 建筑材料学报， 2007， 10( 5) : 516－521．
Zhang Shiping，Deng Min，Wu Jianhua， et al． Analysis of causes for destruction of an airport runway shoulder［J］． Journal of Builiding Materials， 2007， 10( 5) : 516－521．

相似文献/References:

[1]孙亚飞,耿 飞,高培伟,等.掺聚丙烯纤维泡沫混凝土性能与仿真分析[J].南京理工大学学报(自然科学版),2016,40(04):504.[doi:10.14177/j.cnki.32-1397n.2016.40.04.020]
　Sun Yafei,Geng Fei,Gao Peiwei,et al.Properties and simulation analysis of foamed concrete with polypropylene fiber[J].Journal of Nanjing University of Science and Technology,2016,40(04):504.[doi:10.14177/j.cnki.32-1397n.2016.40.04.020]

备注/Memo

备注/Memo:
国家自然科学基金(51178221);国家住建部科学技术项目(2011-K4-24)
更新日期/Last Update: 2012-10-12