[1]黄秋颖,林肖漪,孟祥茹.二维锌配合物的合成、结构及性能研究[J].南京理工大学学报(自然科学版),2017,41(02):232.[doi:10.14177/j.cnki.32-1397n.2017.41.02.015]
 Huang Qiuying,Lin Xiaoyi,Meng Xiangru.Synthesis,structure and property of 2D znic complex[J].Journal of Nanjing University of Science and Technology,2017,41(02):232.[doi:10.14177/j.cnki.32-1397n.2017.41.02.015]
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二维锌配合物的合成、结构及性能研究()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
41卷
期数:
2017年02期
页码:
232
栏目:
出版日期:
2017-04-30

文章信息/Info

Title:
Synthesis,structure and property of 2D znic complex
文章编号:
1005-9830(2017)02-0232-07
作者:
黄秋颖1林肖漪2孟祥茹3
1.河南工业职业技术学院 应用化学工程系,河南 南阳 473009; 2.南阳市第一中学,河南 南阳 473000; 3.郑州大学 化学与分子工程学院,河南 郑州450001
Author(s):
Huang Qiuying1Lin Xiaoyi2Meng Xiangru3
1.Department of Chemical Engineering,Henan Polytechnic Institute,Nanyang 473009,China; 2.No 1 Middle School of Nanyang,Nanyang 473000,China; 3.College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450001,China
关键词:
Zn(II)-配合物 2-(1H-咪唑-1-甲基)-1H-苯并咪唑 123-苯三甲酸钠 晶体结构 热稳定性 荧光性能
Keywords:
Zn(II)-complex 2-(1H-imidazol-1-methyl)-1H-benzimidazole sodium benzene-123-tricarboxylate crystal structure thermal stability fluorescence property
分类号:
O614
DOI:
10.14177/j.cnki.32-1397n.2017.41.02.015
摘要:
以Zn(NO3)2·6H2O、2-(1H-咪唑-1-甲基)-1H-苯并咪唑(imb)和1,2,3-苯三甲酸钠(Na3btc)为原料,在120℃下通过溶剂热法合成一个新的二维结构的配合物{[Zn6(imb)4(btc)4]·7.5H2O}n(1)。通过元素分析、红外光谱、热分析对配合物1进行表征。单晶X-射线衍射分析表明,配合物1为单斜晶系,P21/c空间群。室温固态荧光测试显示,在312 nm激发波长下,该配合物在422 nm处有强荧光发射峰。
Abstract:
A new 2D complex with the formula {[Zn6(imb)4(btc)4]·7.5H2O}n(1)is synthesized through the solvothermal reaction of Zn(NO3)2·6H2O,2-(1H-imidazol-1-methyl)-1H-benzimidazole(imb)and sodium benzene-1,2,3-tricarboxylate(Na3btc)at 120 ℃,and it is structurally characterized by the elemental analysis,the infrared spectroscopy(IR)and the thermogravimetric analysis.The single-crystal X-ray analysis reveals that the complex 1 crystallizes in the monoclinic space group P21/c.Upon excitation at 312 nm,complex powders exhibits intense emission at 422 nm and room temperature for the solid state.

参考文献/References:

[1] Suh M P,Park H J,Prasad T K,et al.Hydrogen storage in metal-organic frameworks[J].Chemical Review,2012,112:782-835.
[2]刘进剑,刘祖亮,蔺向阳,等.2,6-二氨基-3,5-二硝基吡啶-1-氧化物含能配合物的制备及性能研究[J].南京理工大学学报,2013,37(4):640-646.
Liu Jinjian,Liu Zuliang,Lin Xiangyang,et al.Preparation and properties of three novel energetic complexes of 2,6-diamino-3,5-dinitropyridine-1-oxides[J].Journal of Nanjing University of Science and Technology,2013,37(4):640-646.
[3]戴沛霞,葛红光.配合物[Cd(na)2(phen)2]·[Cd(na)2(phen)2]·3H2O的合成、晶体结构及荧光性质[J].硅酸盐通报,2016,35(4 ):1028-1033.
Dai Peixia,Ge Hongguang.Synthesis,crystal structure and fluorescent property of complex[Cd(na)2(phen)2]·[Cd(na)2(phen)2]·3H2O[J].Bulletin of the Chinese Ceramic Society,2016,35(4):1028-1033.
[4]黄秋颖,刘春丽,孟祥茹.二维镉配合物的合成、结构及性能研究[J].南京理工大学学报,2017,41(1):108-115.
Huang Qiuying,Liu Chunli,Meng Xiangru.Synthesis,structure and properties of a 2D Cd(II)complex[J].Journal of Nanjing University of Science and Technology,2017,41(1):108-115.
[5]Maity D K,Halder A,Ghosh S,et al.Azo functionalized 5-nitro-1,3-benzenedicarboxylate based coordination polymers with different dimensionality and functionality[J].Crystal Growth & Design,2016,16:4793-4804.
[6]Yang H X,Liang Z,Hao B L,et al.Syntheses,crystal structures,and characterization of three 1D,2D and 3D complexes based on mixed multidentate N-and O-donor ligands[J].Journal of Solid State Chemistry,2014,218:23-31.
[7]Huang Q Y,Li T,Meng X R.A new 3D cobalt(II)complex with left- and right-handed helical channels[J].Inorganic Chemistry Communications,2014,49:52-55.
[8]刘絮,张宇虹,孟祥茹.三维Cu(II)配合物的合成、结构及性能研究[J].河南科学,2016,34(6):861-865.
Liu Xu,Zhang Yuhong,Meng Xiangru.Synthesis,structure and property of a 3D Cu(II)complex[J].Henan Science,2016,34(6):861-865.
[9]Katritzky A R,Drewniak-Deyrup M,Lan X F,et al.Preparation,lithiation and transformation of N-(benzotriazol-1-ylmethyl)heterocycle[J].Journal of Heterocyclic Chemistry,1989,26:829-836.
[10]Sheldrick G M.A short history of SHELX[J].Acta Crystallographica,2008,A64:112-122.
[11]Addison A W,Rao T N,Reedijk J,et al.Synthesis,structure,and spectroscopic properties of copper(II)compounds containing nitrogen-sulphur donor ligands; the crystal and molecular structure of aqua[l,7-bis(N-methylbenzimidazol-2’-yl)-2,6-dithiaheptane]copper(II)perchlorate[J].Journal of the Chemical Society,Faraday Transactions,1984:1349-1356.
[12]闫丽,王米嘉.N-(2-氧乙酸-3-甲氧基)苄叉二胺合锌(II)配合物的合成、晶体结构及光学性质研究[J].无机化学学报,2013,29(11):2370-2374.
Yan Li,Wang Mijia.Synthesis,crystal structures and fluorescence of two Zn(II)complexes with schiff base ligands[J].Chinese Journal of Inorganic Chemistry,2013,29(11):2370-2374.
[13]Huang Q Y,Wang X X,Li T,et al.Construction of zinc-organic frameworks by flexible aliphatic dicarboxylates plus 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole ligand[J].Journal of Coordination Chemistry,2015,68(1):88-105.
[14]Yang Y Q,Su C F,Zhang J D,et al.Construction of Cd(II)complexes based on 2-(1Himidazol-1-methyl)-1H-benzimidazole and 1,4-benzenedicarboxylate[J].Journal of Coordination Chemistry,2016,69(24):3762-3775.
[15]Bai H Y,Ma J F,Yang J,et al.Effect of anions on the self-assembly of Cd(II)-containing coordination polymers based on a novel flexible tetrakis(imidazole)ligand[J].Crystal Growth & Design,2009,10(2):995-1015.

备注/Memo

备注/Memo:
收稿日期:2016-12-07 修回日期:2017-01-21
基金项目:国家自然科学基金(J1210060); 河南省教育厅基础与前沿技术研究计划资助项目(16B150002); 河南省科技厅基础与前沿技术研究项目(162300410206); 河南省科技攻关项目(172102210128)
作者简介:黄秋颖(1972-),女,副教授,主要研究方向:功能配位化学,E-mail:huangqy72@163.com。
引文格式:黄秋颖,林肖漪,孟祥茹.二维锌配合物的合成、结构及性能研究[J].南京理工大学学报,2017,41(2):232-238.
投稿网址:http://zrxuebao.njust.edu.cn
更新日期/Last Update: 2017-04-30