[1]钟秦.湿法烟气脱硫的理论和实验研究Ⅲ──工艺实验和脱硫模型的验证[J].南京理工大学学报(自然科学版),1999,(02):65-69.
 Zhong Qin.Theoretical and Experimental Investigation of Wet Flue Gas Desulfurization The Technological Experiments and Verification of Desulfurization Model[J].Journal of Nanjing University of Science and Technology,1999,(02):65-69.
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湿法烟气脱硫的理论和实验研究Ⅲ──工艺实验和脱硫模型的验证()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
期数:
1999年02期
页码:
65-69
栏目:
出版日期:
1999-04-30

文章信息/Info

Title:
Theoretical and Experimental Investigation of Wet Flue Gas Desulfurization The Technological Experiments and Verification of Desulfurization Model
作者:
钟秦
南京理工大学化工学院, 南京210094
Author(s):
Zhong Qin
School of Chemical Engineering,NUST,Nanjing210094
关键词:
烟气脱硫 石灰石 石灰 强制氧化 自然氧化
Keywords:
f lue g as desulfurization limestone lime forced-ox idat ion natura-l oxidat ion
分类号:
X511
摘要:
石灰石或石灰湿法烟气脱硫(WFGD) 在中试湿壁吸收塔中被实验研究。实验结果表明, 石灰比石灰石有更强的脱硫反应活性。石灰工艺的L / G 比可以比石灰石的控制得低些, 适合的pH 值操作范围分别是5.5~ 6.2 和5.0~ 5.5。以中试湿壁塔为原型的石灰石WFGD 模型预测的沿塔脱硫率和浆液pH 值的变化、L / G 比和pH 值对脱硫率的影响能较好地与实验数据吻合。石灰石WFGD 强制氧化工艺比自然氧化工艺具有更高的脱硫率。强制氧化的副产物97 % 以上为石膏, 其颗粒的名义直径为3.2 μm, 而自然氧化的副产物主要是亚硫酸氢钙和 10 % 以下的石膏, 其颗粒的名义直径为2.1 μm。
Abstract:
Limestone or lime w et flue gas desulfurization (WFGD) w as invest igated in a p-i lot-scale w et ted-w all column. The experimental result s show that the lime process has higher removal ef ficiency of SO2 than the limestone process. The lime process can be operated at a low er L / G rat io than the limestone process. The suitable operat ing rang es of pH for lime and limestone are 5.5~ 6. 2 and 5. 0~ 5. 5, respect ively. T he limestone WFGD model, based on the p-i lot-scale w et ted-w all column, w as verif ied w ith experiment s. The model predict ions are in good agreement w ith the experimental data such as the deg ree of desulfurization and slurry pH-prof ile along the column, and the effect s of L / G rat io and pH value on SO2 removal. The forced-ox idat ion mode of limestone WFGD has hig her removal eff iciency of SO2 than the natura-l oxidation mode. The by-product f rom the forced-oxidation is gy psum that contains above 97 % CaSO4·2H2O. T he mean diameter of gypsum crystals is 32 μm. The by-product from the natura-l ox idat ion is a mix ture of calcium bisulf ite and below 10 % gy psum which has the mean diameter of 2. 1 μm.

参考文献/References:

1 钟秦. 湿法烟气脱硫的理论和实验研究Ⅰ ——湿壁塔脱硫反应系统及操作特性. 南京理工大学学报, 1998, 22( 6) : 517~ 520
2 钟秦. 湿法烟气脱硫的理论和实验研究Ⅱ ——湿壁塔烟气脱硫数学模型. 南京理工大学学报, 1999, 23( 1) : 1~ 5
3 Gage C L, Ro chelle G T. Limestone dissolution in flue g as scrubbing: effect of sulfite. J Air Waste Management Assoc, 1992, 42: 7~ 12
4 Clar ke L B. Manag ement o f FGD residues. London: IEA Coal Research, 1993. 61~ 67

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备注/Memo

备注/Memo:
国家留学基金,江苏省青年科技基金
钟 秦 男 35 岁 博士
更新日期/Last Update: 2013-03-29