[1]黄秋颖,江金永,李姗珊,等.基于氮杂环和羧酸配体的银(I)配合物的合成、结构及性能[J].南京理工大学学报(自然科学版),2017,41(04):533.[doi:10.14177/j.cnki.32-1397n.2017.41.04.020]
 Huang Qiuying,Jiang Jinyong,Li Shanshan,et al.Synthesis,structure and properties of a Ag(I)complex based onN-heterocyclic and carboxylic acid ligands[J].Journal of Nanjing University of Science and Technology,2017,41(04):533.[doi:10.14177/j.cnki.32-1397n.2017.41.04.020]
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基于氮杂环和羧酸配体的银(I)配合物的合成、结构及性能()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
41卷
期数:
2017年04期
页码:
533
栏目:
出版日期:
2017-08-31

文章信息/Info

Title:
Synthesis,structure and properties of a Ag(I)complex based onN-heterocyclic and carboxylic acid ligands
文章编号:
1005-9830(2017)04-0533-06
作者:
黄秋颖1江金永2李姗珊1孟祥茹3
1.河南工业职业技术学院 应用化学工程系,河南 南阳 473009; 2.河南省核工业地质局,河南 郑州 450044; 3.郑州大学 化学与分子工程学院,河南 郑州 450001
Author(s):
Huang Qiuying1Jiang Jinyong2Li Shanshan1Meng Xiangru3
1.Department of Chemical Engineering,Henan Polytechnic Institute,Nanyang 473009,China; 2.Henan Province Nuclear Geology,Zhengzhou 450044,China; 3.College of Chemistry and Molecular Engineering,Zhengzhou University,Zhengzhou 450001,China
关键词:
Ag(I)-配合物 2-(1H-咪唑-1-甲基)-1H-苯并咪唑 135-苯三甲酸 晶体结构 热稳定性 荧光性
Keywords:
Ag(I)-complex 2-(1H-imidazol-1-methyl)-1H-benzimidazole 135-benzene-tricarboxylic acid crystal structure thermal stability fluorescence property
分类号:
O614
DOI:
10.14177/j.cnki.32-1397n.2017.41.04.020
摘要:
以AgNO3·H2O、2-(1H-咪唑-1-甲基)-1H-苯并咪唑(imb)和1,3,5-苯三甲酸(H3btc)为原料,在120 ℃下通过溶剂热法合成了一个新的配合物[Ag3(Hbtc)(H2btc)(imb)2](1)。并通过元素分析、红外光谱、热分析对配合物1进行了表征。单晶X-射线衍射分析表明,配合物1为三斜晶系,P-1空间群,在256 ℃以前很稳定。室温固态荧光测试显示,在313 nm激发波长下,配合物1在419 nm具有较强的荧光发射峰。
Abstract:
A new complex with the formula[Ag3(Hbtc)(H2btc)(imb)2](1)is synthesized through the reaction of AgNO3·H2O with 2-(1H-imidazol-1-methyl)-1H-benzimidazole(imb)and 1,3,5-benzenetricarboxylic acid(H3btc)under solvothermal condition at 120 ℃,structurally characterized by elemental analysis,IR spectra and thermogravimetric analysis.Single-crystal X-ray analysis reveals that complex 1 crystallizes in triclinic space group P-1.There is no obvious weight loss until 256 ℃.Upon the excitation at 313 nm,the powder X-ray diffraction patterns of complex 1 exhibite intense emission centered at 419 nm in the solid state at room temperature.

参考文献/References:

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相似文献/References:

[1]黄秋颖,刘春丽,孟祥茹.二维层状镉配合物的合成、结构及性能[J].南京理工大学学报(自然科学版),2017,41(01):108.[doi:10.14177/j.cnki.32-1397n.2017.41.01.015]
 Huang Qiuying,Liu Chunli,Meng Xiangru.Synthesis,structure and properties of two-dimensionallayered Cd(Ⅱ)complex[J].Journal of Nanjing University of Science and Technology,2017,41(04):108.[doi:10.14177/j.cnki.32-1397n.2017.41.01.015]

备注/Memo

备注/Memo:
收稿日期:2017-03-10 修回日期:2017-03-25基金项目:国家自然科学基金(J1210060); 河南省教育厅基础与前沿技术研究计划项目资助(16B150002); 河南省科技攻关项目(172102210128)
作者简介:黄秋颖(1972-),女,副教授,主要研究方向:功能配位化学,E-mail:huangqy72@163.com。
引文格式:黄秋颖,江金永,李姗珊,等.基于氮杂环和羧酸配体的银(I)配合物的合成、结构及性能[J].南京理工大学学报,2017,41(4):533-538.
投稿网址:http://zrxuebao.njust.edu.cn
更新日期/Last Update: 2017-08-31