[1]唐 静,杨 轶,徐梦鸽,等.基于氮杂环和羧酸配体的三维镉(Ⅱ)金属有机框架的合成、结构及性能[J].南京理工大学学报(自然科学版),2019,43(04):535-540.[doi:10.14177/j.cnki.32-1397n.2019.43.04.022]
 Tang Jing,Yang Yi,Xu Mengge,et al.Synthesis,structure and properties of a 3D Cd(Ⅱ)MOF based onN-heterocyclic and carboxylic acid ligands[J].Journal of Nanjing University of Science and Technology,2019,43(04):535-540.[doi:10.14177/j.cnki.32-1397n.2019.43.04.022]
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基于氮杂环和羧酸配体的三维镉(Ⅱ)金属有机框架的合成、结构及性能()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
43卷
期数:
2019年04期
页码:
535-540
栏目:
出版日期:
2019-08-24

文章信息/Info

Title:
Synthesis,structure and properties of a 3D Cd(Ⅱ)MOF based onN-heterocyclic and carboxylic acid ligands
文章编号:
1005-9830(2019)04-0523-06
作者:
唐 静杨 轶徐梦鸽乔子洋余思冀黄秋颖
河南工业职业技术学院 应用化学工程系,河南 南阳 473009
Author(s):
Tang JingYang YiXu MenggeQiao ZiyangYu SijiHuang Qiuying
Department of Chemical Engineering,Henan Polytechnic Institute,Nanyang 473009,China
关键词:
镉(Ⅱ)金属有机框架 晶体结构 热分析 荧光性能
Keywords:
Cd(Ⅱ)-metal-organic framework structure analysis thermogravimetric behavior fluorescence characteristics
分类号:
O614
DOI:
10.14177/j.cnki.32-1397n.2019.43.04.022
摘要:
以含有柔性基团的苯并咪唑衍生物2-(1H-咪唑-1-甲基)-6-甲基-1H-苯并咪唑(immb)和芳香二羧酸对苯二甲酸(H2bdic)为配体,以CdCl2·2.5H2O为金属源,通过水热法合成出了一个新的金属有机框架(MOF)[Cd(bdic)(immb)]n(1)。单晶X-射线衍射分析表明,该MOF为单斜晶系,C2/c空间群。桥联配体immb和bdic2-同时与Cd(Ⅱ)离子配位形成三维网状结构,其拓扑符号为(42·63·8)。红外光谱以及热分析的结果与单晶X-射线衍射分析的结果一致。室温固态荧光光谱测定结果表明,标题MOF具有良好的荧光性能。
Abstract:
Hydrothermal reaction of CdCl2·2.5H2O with flexible benzimidazole derivative 2-(1H-imidazol-1-methyl)-6-methyl-1H-benzimidazole(immb)and aromatic polycarboxylic ligand 1,4-benzenedicarboxylic acid(H2bdic)result in a new metal-organic framework(MOF)[Cd(bdic)(immb)]n(1). The results of X-ray crystallographic analysis reveal that this MOF crystallizes in the monoclinic space group C2/c. Cd(Ⅱ)ions are linked by immb and bdic2- ligands leading to a 3D structure with the topological notation of(42·63·8). The IR spectrum and thermogravimetric curve are consistent with the results of the X-ray crystal structure analysis. In addition,the powder of the MOF exhibits good fluorescence at room temperature.

参考文献/References:

[1] Agarwal R A,Gupta N K. CO2 sorption behavior of imidazole,benzimidazole and benzoic acid based coordination polymers[J]. Coordination Chemistry Reviews,2017,332:100-121.
[2]Tomar K. Assembly of an imidazole templated indium-oxalate porous 3D framework with tcj/hc topology:Synthesis,structure and sorption property[J]. Inorganic Chemistry Communications,2015,54:63-65.
[3]Huang Q Y,Wang X X,Li T,et al. Construction of zinc-organic frameworks by flexible aliphatic dicarboxylates plus 2-(1H-imidazolyl-1-methyl)-1H benzimidazole ligand[J]. Journal of Coordination Chemistry,2015,68(1):88-105.
[4]Wang Y T,Tang G M,Wei Y Q,et al. Two new nonlinear optical and ferroelectric three-dimensional metal-organic frameworks with an sqp-net[J]. Crystal Growth & Design,2010,10(1):25-28.
[5]Yang H X,Liang Z,Hao B L,et al. Syntheses,crystal structures,and characterization of three 1D,2D and 3D complexes based on mixed multidentate N-and O-donor ligands[J]. Journal of Solid State Chemistry,2014,218:23-31.
[6]Zhang G Y,Zhou X L,Li T,et al. Three Cd complexes based on 2-(1H-imidazol-1-methyl)-1H-benzimidazole and homologous aliphatic dicarboxylates[J]. Inorganica Chimica Acta,2014,421:45-51.
[7]Zhang Y H,Zhang Q J,Wen Y,et al. Crystal structures and luminescence properties of two Cd(Ⅱ)complexes based on 2-(1H-imidazol-1-methyl)-6-methyl-1H-benzimidazole[J]. Zeitschrift fur Naturforschung B,2015,70b(8):577-585.
[8]Huang Q Y,Zhao Y,Meng X R. Syntheses,structures and characterization of isomorphous Co and NIII coordination polymers based on 2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole and benzene-1,4-dicarboxylate[J]. Acta Crystallographica Section C,2017,73:645-651.
[9]Yang H X,Yang Y Q,Cheng D,et al. A new two-dimensional Cd coordination polymer based on 2-(1H-imidazol-1-ylmethyl)-6-methyl-1H-benzimidazole and benzene-1,2-dicarboxylate:synthesis,crystal structure and characterization[J]. Acta Crystallographica Section C,2017,73:828-832.
[10]Liang Z,Jian S J,Zhou J H,et al. Crystal structure of poly[[u2-1,2-benzenedicarboxylato-κ4O,O’:O″,O]-[u2-2-((1H-imidazol-1-yl)-6-methyl)-1H-benzoimidazole-κ2N:N’]-cadmium(Ⅱ)],C20H15CdN4O4[J]. Zeitschrift fur Kristallograhie-New Crystral Stuctures,2015,230(3):203-204.
[11]Meng X R,Wu X J,Li D W,et al. Influence of the anion on the coordination mode of an unsymmetrical N-heterocyclic ligand in Cd(Ⅱ)complexes:From discrete molecule to one-and two-dimensional structures[J]. Polyhedron,2010,29:2619-2628.
[12]Rigaku/MSC. CrystalClear. Rigaku/MSC. The Woodlands,Texas,USA,2004.
[13]Sheldrich G M. A short history of SHELX[J]. Acta Crystallographica Section A,2008,64:112-122.
[14]Sheldrich G M. Crystal structure refinement with SHELXL[J]. Acta Crystallographica Section C,2015,71:3-8.
[15]Huang Q Y,Tang W P,Liu C L,et al. Syntheses,structures,and properties of two 2-D Cd(Ⅱ)complexes based on 2-(1H-imidazol-1-methyl)-1H-benzimidazole and polycarboxylate ligands[J]. Journal of Coordination Chemistry,2014,67(1):149-161.
[16]Dolomanov O V,Blake A J,Champness N R,et al. OLEX:New software for visualization and analysis of extended crystal structures[J]. Journal of Applied Crystallography,2003,36:1283-1284.
[17]黄秋颖,刘春丽,孟祥茹. 二维层状镉配合物的合成、结构及性能[J]. 南京理工大学学报,2017,41(1):108-115.
Huang Qiuying,Liu Chunli,Meng Xiangru. Synthesis,structure and properties of a 2D Cd(Ⅱ)complex[J]. Journal of Nanjing University of Science and Technology,2017,41(1):108-115.
[18]黄秋颖,林肖漪,孟祥茹. 二维锌配合物的合成、结构及性能研究[J]. 南京理工大学学报,2017,41(2):232-238.
Huang Qiuying,Lin Xiaoyi,Meng Xiangru. Synthesis,structure and properties of a 2D znic complex[J]. Journal of Nanjing University of Science and Technology,2017,41(2):232-238.
[19]黄秋颖,江金永,李姗珊,等. 基于氮杂环和羧酸配体的银(I)配合物的合成、结构及性能[J]. 南京理工大学学报,2017,41(4):533-538.
Huang Qiuying,Jiang Jinyong,Li Shanshan,et al. Synthesis,structure and properties of a Ag(I)complex based on N-heterocyclic and carboxylic acid ligands[J]. Journal of Nanjing University of Science and Technology,2017,41(4):533-538.

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备注/Memo

备注/Memo:
收稿日期:2018-11-30 修回日期:2019-06-02
基金项目:国家自然科学基金(21771163); 河南省科技厅科技攻关项目(172102210128)
作者简介:唐静(1982-),女,助教,主要研究方向:配位化学,E-mail:jingtang0701@163.com; 通讯作者:黄秋颖(1972-),女,教授,主要研究方向:功能配位化学,E-mail:huangqy72@163. com。
引文格式:唐静,杨轶,徐梦鸽,等. 基于氮杂环和羧酸配体的三维镉(Ⅱ)金属有机框架的合成、结构及性能[J]. 南京理工大学学报,2019,43(4):535-540.
投稿网址:http://zrxuebao.njust.edu.cn
更新日期/Last Update: 2019-09-30