[1]宋志国,张 顺,张皜昊,等.苯磺酸锌配合物晶体结构和荧光性能研究[J].南京理工大学学报(自然科学版),2019,43(05):654-659.[doi:10.14177/j.cnki.32-1397n.2019.43.05.016]
 Song Zhiguo,Zhang Shun,Zhang Haohao,et al.Study on crystal structure and fluorescence propertyof zinc complex with benzenesulfonic acid[J].Journal of Nanjing University of Science and Technology,2019,43(05):654-659.[doi:10.14177/j.cnki.32-1397n.2019.43.05.016]
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苯磺酸锌配合物晶体结构和荧光性能研究()
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《南京理工大学学报》(自然科学版)[ISSN:1005-9830/CN:32-1397/N]

卷:
43卷
期数:
2019年05期
页码:
654-659
栏目:
出版日期:
2019-10-31

文章信息/Info

Title:
Study on crystal structure and fluorescence propertyof zinc complex with benzenesulfonic acid
文章编号:
1005-9830(2019)05-0654-06
作者:
宋志国1张 顺2张皜昊2王 敏2
渤海大学 1.实验管理中心; 2化学化工学院,辽宁 锦州 121013
Author(s):
Song Zhiguo1Zhang Shun2Zhang Haohao2Wang Min2
1.Center of Experimental Management; 2.College of Chemistry & Chemical Engineering,Bohai University,Jinzhou 121013,China
关键词:
苯磺酸锌 配合物 晶体结构 荧光
Keywords:
zinc benzenesulfonate complexes crystal structure fluorescence
分类号:
O614.24
DOI:
10.14177/j.cnki.32-1397n.2019.43.05.016
摘要:
该文采用溶剂挥发法得到两个过渡金属配合物苯磺酸锌[Zn(H2O)6](C6H5SO3)2(1)和对甲基苯磺酸锌[Zn(H2O)6](p-CH3C6H4SO3)2(2),均为无色块状晶体。采用红外光谱、核磁共振光谱、热重分析和X-射线单晶衍射法对两个配合物的结构进行了表征。结果表明,两个配合物均为单斜晶系,P21/c空间群,配合物中Zn(Ⅱ)离子均与6个配位水分子中的氧原子配位,形成畸形的八面体空间构型,再通过氢键和π-π堆积作用形成三维超分子结构。还研究了两个配合物的固体荧光性能。
Abstract:
Two transition metal complexes including zinc benzenesulfonate[Zn(H2O)6](C6H5SO3)2(1)and zinc p-tolylsulfonate[Zn(H2O)6](p-CH3C6H4SO3)2(2)are obtained by the slow evaporation method in water,and the two products are all the colorless block crystal. The structures of the two complexes are characterized by infraved radiation(IR),nudear magnetic resonance(NMR),thermal gravimetric analysis(TGA)and X-ray single crystal diffraction. The results show that the two complexes belong to the monoclinic system and the space group P21/c. The Zn(Ⅱ)ions in the two complexes all coordinate with the oxygen atoms in the six coordination water molecules to form a deformed octahedral spatial configuration. They extend to a three-dimensional supramolecular structure through hydrogen bonds and π-π interactions. In addition,the solid-state fluorescent properties of two complexes are studied.

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相似文献/References:

[1]张 防,等.1,4-苯二甲酸镉的合成及其热分解制备CdO纳米晶[J].南京理工大学学报(自然科学版),2009,(01):137.
 ZHANG Fang,BEI Feng-li,LIU Xiao-heng,et al.Preparation of Nano-sized Crystal CdO by Thermal Decomposition of Cadmium Complex of 1,4-Benzene Dicarboxylic Acid[J].Journal of Nanjing University of Science and Technology,2009,(05):137.
[2]陆路德,杨绪杰,顾蔚红,等.席夫碱配合物的研究(Ⅲ)——Fe(Ⅲ)配合物的循环伏安特性[J].南京理工大学学报(自然科学版),1990,(04):56.
 Lu Lude.Studies on Schiff Base Complexes Fe(Ⅲ)——Cyclic Voltammetric Behavior of Fe(Ⅲ)Complexes[J].Journal of Nanjing University of Science and Technology,1990,(05):56.

备注/Memo

备注/Memo:
收稿日期:2018-07-22 修回日期:2018-10-08
基金项目:辽宁省自然科学基金(2019-MS-005); 辽宁省教育厅项目(LJ2019007); 国家自然科学基金(21707009)
作者简介:宋志国(1975-),男,高级实验师,主要研究方向:绿色催化,E-mail:lnbhu@hotmail.com。
引文格式:宋志国,张顺,张皜昊,等. 苯磺酸锌配合物晶体结构和荧光性能研究[J]. 南京理工大学学报,2019,43(5):654-659.
投稿网址:http://zrxuebao.njust.edu.cn
更新日期/Last Update: 2019-11-30